Polarimetry Calculator: [α]D, OP, ee%, %R,%S
(1) eq1: [α]D Specific Rotation of Enantiomer : Sample's rotation =
° ⇒ Length of cell (dm) =
⇒ Goto (2)
(2) Concentration (g/ml) =
⇒
Specific rotation [α]D =
°
(3) Optical Purity : Sample's [α]D =
° ⇒ Enantiomers highest [α]D =
° ⇒
=
(4) Enantiomeric Excess (ee) : % Predominant enantiomer (>50) =
⇒
=
%
(5) % Predominant Enantiomer from Enantiomeric Excess (ee) :
♦ Decimal places:
1
2
(6) ee =
% ⇒
⇒ % R or S =
 
(7) eq3: Optical Rotation: Major enantiomer proportion P1 =
⇒ [α 1]D
° ⇒
[αM]D =
°
(8) eq4: % R and S enantiomers : Sample's Specific [αM]D Rotation =
° ⇒ Goto (9)
(9) Maximum known S [α]D =
° ⇒
R % =
S % =
(10) eq5: Specific [α 1]D Rotation of enantiomer with one chiral impurity : Enantiomer Proportion =
⇒ Goto (11)
(11) Specific [αM]D of mix =
° ⇒ Known [α 2]D impurity =
° ⇒
of Enantiomer =
°
(12) eq6: Highest Specific [α]D Rotation of Mix of two Enantiomers :
(13) Proportion major enantiomer =
⇒ Specific [αM]D of mixture =
° ⇒
=
°
(14) Adjust [α 1]D of enantiomer in mixture with chiral impurities or predict rotation of mix [αM]D :
(15) eq7: [αM]D,P1,[α 2],P2,[α 3]D,P3,...
⇒
Adjusted [α 1]D =
°
(16) eq8: [α 1]D,P1,[α 2],P2,[α 3]D,P3,...
⇒
[αM]D of mix =
°
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